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Publikationen

  1. "Hydroamination of Alkenes" Reznichenko, A. L.; Hultzsch, K. C. in Organic Reactions; S. E. Denmark, A. Charette, Eds.; Wiley: Hoboken, NJ, 2016, 1-554. PDF

  2. "σ-Insertive Mechanism versus Concerted Non-insertive Mechanism in the Intramolecular Hydroamination of Aminoalkenes Catalyzed by Phenoxyamine Magnesium Complexes: A Synthetic and Computational Study" Zhang, X.; Tobisch, S.; Hultzsch, K. C. Chem. Eur. J. 2015, 21, 7841-7857. PDF
    Hotpaper

  3. "Asymmetric Hydroamination" Reznichenko, A. L.; Nawara-Hultzsch, A. J.; Hultzsch, K. C. Top. Curr. Chem. 2014, 343, 191-260. PDF
  4. "C1-Symmetric Rare Earth Metal Aminodiolate Complexes for Intra- and Intermolecular Asymmetric Hydroamination" Reznichenko, A. L.; Hultzsch, K. C. Organometallics 2013, 32, 1394-1408. PDF

  5. "Early Transition Metal (Group 3-5, Lanthanides and Actinides) and Main Group Metal (Group 1, 2, and 13) Catalyzed Hydroamination" Reznichenko, A. L.; Hultzsch, K. C. Top. Organomet. Chem. 2013, 43, 51-114. PDF
  6. "The Mechanism of Hydroaminoalkylation Catalyzed by Group 5 Metal Binaphtholate Complexes" Reznichenko, A. L.; Hultzsch, K. C. J. Am. Chem. Soc. 2012, 134, 3300-3311. PDF

  7. "A Chiral Phenoxyamine Magnesium Catalyst for the Enantioselective Hydroamination/Cyclization of Aminoalkenes and Intermolecular Hydroamination of Vinyl Arenes" Zhang, X.; Emge, T. J.; Hultzsch, K. C. Angew. Chem. Int. Ed. 2012, 51, 394-398; Angew. Chem. 2012, 124, 406-410. English PDF German PDF
    VIP Artikel mit Frontispiz (siehe Angew. Chem. Int. Ed. (Jahrgang 51, Ausgabe 2, 9. Jänner 2012).

  8. "Group 5 Metal Binaphtholate Complexes for the Catalytic Asymmetric Hydroaminoalkylation and Hydroamination/Cyclization" Reznichenko, A. L.; Emge, T. J.; Audörsch, S.; Klauber, E. G.; Hultzsch, K. C.; Schmidt, B. Organometallics 2011, 30, 921-924. PDF
    Diese Arbeit wurde auf dem Titelbild von Organometallics (Jahrgang 30, Ausgabe 5, 11. März 2011) hervorgehoben.

  9. "Linked Bis(β-Diketiminato) Yttrium and Lanthanum Complexes as Catalysts in Asymmetric Hydroamination/Cyclization of Aminoalkenes (AHA)" Vitanova, D. V.; Hampel, F.; Hultzsch, K. C. J. Organomet. Chem. 2011, 696, 321-330. PDF

  10. "Intramolecular Aminoalkene Hydroamination Catalyzed by Magnesium Complexes Containing Multidentate Phenoxyamine Ligands" Zhang, X.; Emge, T. J.; Hultzsch, K. C. Organometallics 2010, 29, 5871-5877. PDF

  11. "Asymmetric Intermolecular Hydroamination of Unactivated Alkenes with Simple Amines" Reznichenko, A. L.; Nguyen, H. N.; Hultzsch, K. C. Angew. Chem. Int. Ed. 2010, 49, 8984-8987; Angew. Chem. 2010, 122, 9168-9171. English PDF German PDF
    Diese Arbeit wurde in Synfacts (Ausgabe 2, Februar 2011, S. 0176) diskutiert.

  12. "Hydroamination, Hydrophosphination, Hydrophosphinylation, and Hydrophosphonylation of Carbon-Carbon Double Bonds" Reznichenko, A. L.; Hultzsch, K. C. in Science of Synthesis Reference Library: Stereoselective Synthesis; J. G. de Vries, Ed.; Thieme: Stuttgart, 2010, 689-729.
  13. "Catalytic σ-bond Metathesis" Reznichenko, A. L.; Hultzsch, K. C. Struct. Bond.2010, 137, 1-48. PDF
  14. "Asymmetric Hydroamination" Reznichenko, A. L.; Hultzsch, K. C. in Chiral Amine Synthesis: Methods, Developments and Applications; T. Nugent, Ed.; Wiley-VCH: Weinheim, 2010, 341-375. PDF
  15. "C2-Symmetric Zirconium Bis(Amidate) Complexes with Enhanced Reactivity in Aminoalkene Hydroamination" Reznichenko, A. L.; Hultzsch, K. C. Organometallics 2010, 29, 24-27. PDF

  16. "Kinetic Resolution of Aminoalkenes via Asymmetric Hydroamination (AHA): A Mechanistic Study" Reznichenko, A. L.; Hampel, F.; Hultzsch, K. C. Chem. Eur. J. 2009, 15, 12819-12827. PDF

  17. "Intramolecular Hydroamination/Cyclization of Aminoalkenes Catalyzed by Diamidobinaphthyl Magnesium- and Zinc-Complexes" Horrillo-Martínez, P.; Hultzsch, K. C. Tetrahedron Lett. 2009, 50, 2054-2056. PDF

  18. "Imido and Amidotitanium Complexes that Contain a [OSSO]-Type Bis(phenolato) Ligand: Synthesis, Structures, and Hydroamination Catalysis" Lian, B.; Spaniol, T. P.; Horrillo-Martínez, P.; Hultzsch, K. C.; Okuda, J. Eur. J. Inorg. Chem. 2009, 429-434. PDF

  19. "Hydroamination: Direct Addition of Amines to Alkenes and Alkynes" Müller, T. E.; Hultzsch, K. C.; Yus, M.; Foubelo, F.; Tada, M. Chem. Rev. 2008, 108, 3795-3892. PDF
  20. "Synthesis and Structural Characterization of β-Diketiminato Yttrium Complexes and their Application in Epoxide/CO2-Copolymerization" Lazarov, B. B.; Hampel, F.; Hultzsch, K. C. Z. Anorg. Allg. Chem. 2007, 633, 2367-2373. PDF
  21. "Dinuclear Zinc Complexes Based on Parallel β-Diiminato Binding Sites: Syntheses, Structures and Properties as Co-polymerisation Catalysts" Pilz, M. F.; Limberg, C.; Lazarov, B. B.; Hultzsch, K. C.; Ziemer, B. Organometallics 2007, 26, 3668-3676. PDF

  22. "(+)-Neomenthyl- and (–)-phenylmenthyl-substituted cyclopentadienyl and indenyl yttrocenes as Catalysts in asymmetric hydroamination/cyclization of aminoalkenes (AHA)." Vitanova, D. V.; Hampel, F.; Hultzsch, K. C. J. Organomet. Chem. 2007, 692, 4690-4701. PDF

  23. "Base-Catalyzed Anti-Markovnikov Hydroamination of Vinyl Arenes – Scope, Limitations and Computational Studies" Horrillo-Martínez, P.; Hultzsch, K. C.; Gil, A.; Branchadell, V. Eur. J. Org. Chem. 2007, 3311-3325. PDF

  24. "Base catalysed asymmetric hydroamination/cyclisation of aminoalkenes utilising a chiral dimeric diamidobinaphthyl dilithium salt" Horrillo Martínez, P.; Hultzsch, K. C.; Hampel, F. Chem. Commun. 2006, 2221-2223. PDF
    Diese Arbeit wurde auf dem Innencover von Chemical Communications (Ausgabe 21, 4. Juni 2006) hervorgehoben.

  25. "3,3’-Bis(trisarylsilyl)-Substituted Binaphtholate Rare Earth Metal Catalysts for Asymmetric Hydroamination" Gribkov, D. V.; Hultzsch, K. C.; Hampel, F. J. Am. Chem. Soc. 2006, 128, 3748-3759. PDF

  26. "Rare Earth Metal Complexes Based on β-Diketiminato and Novel Linked Bis(β-Diketiminato) Ligands: Synthesis, Structural Characterization and Catalytic Application in Epoxide/CO2-Copolymerization." Vitanova, D. V.; Hampel, F.; Hultzsch, K. C. J. Organomet. Chem. 2005, 690, 5182-5197. PDF

  27. "Catalytic asymmetric hydroamination of non-activated olefins" Hultzsch, K. C. Org. Biomol. Chem. 2005, 3, 1819-1824. PDF
    Diese Arbeit wurde auf dem Titelbild von Organic Biomolecular Chemistry (Jahrgang 3, Ausgabe 10, 21. Mai 2005) hervorgehoben.

  28. "Synthesis and structural characterisation of novel linked bis(β-diketiminato) rare earth metal complexes" Vitanova, D. V.; Hampel, F.; Hultzsch, K. C. Dalton Trans. 2005, 1565-1566. PDF

  29. "Non-Metallocene Rare Earth Metal Catalysts for the Diastereoselective and Enantioselective Hydroamination of Aminoalkenes" Hultzsch, K. C.; Gribkov, D. V.; Hampel, F. J. Organomet. Chem. 2005, 690, 4441-4452. PDF

  30. "Transition Metal-Catalyzed Asymmetric Hydroamination of Alkenes (AHA)" Hultzsch, K. C.; Adv. Synth. Catal., 2005, 347, 367-391. PDF

  31. "Hydroamination/Cyclization of Aminoalkenes Using Cationic Zirconocene and Titanocene Catalysts" Gribkov, D. V.; Hultzsch, K. C. Angew. Chem. Int. Ed. 2004, 43, 5542-5546; Angew. Chem. 2004, 116, 5659-5663. English PDF German PDF

  32. "Optical Spectroscopy of Long Polyenes" Christensen, R. L.; Faksh, A.; Meyers, J. A.; Samuel, I. D. W.; Wood, P.; Schrock, R. R.; Hultzsch, K. C. J. Phys. Chem. A 2004, 108, 8229-8236. PDF
  33. "Synthesis and Characterization of Biphenolate Alkyllanthanum Complexes as Catalysts for Hydroamination/Cyclization and Hydrosilylation" Gribkov, D. V.; Hampel, F.; Hultzsch, K. C. Eur. J. Inorg. Chem. 2004, 4091-4101. PDF
  34. "Supported Chiral Mo-Based Complexes as Efficient Catalysts for Enantioselective Olefin Metathesis" Dolman, S. J.; Hultzsch, K. C.; Prezet, F.; Teng, X.; Hoveyda, A. H; Schrock, R. R. J. Am. Chem. Soc. 2004, 126, 10945-10953. PDF
  35. "New Yttrium Complexes Bearing Diamidoamine Ligands as Efficient and Diastereoselective Catalysts for the Intramolecular Hydroamination of Alkenes and Alkynes" Hultzsch, K. C.; Hampel, F.; Wagner, T. Organometallics 2004, 23, 2601-2612. PDF

  36. "Investigations of Reactions between Chiral Molybdenum Imido Alkylidene Complexes and Ethylene: Observation of Unsolvated Base-Free Methylene Complexes, Metalacyclobutane and Metalacyclopentane Complexes, and Molybdenum(IV) Olefin Complexes" Tsang, W. C. P.; Jamieson, J. Y.; Aeilts, S. L.; Hultzsch, K. C.; Schrock, R. R.; Hoveyda, A. H Organometallics 2004, 23, 1997-2007. PDF
  37. "Kinetic resolution of chiral aminoalkenes via asymmetric hydroamination/cyclisation using binaphtholate yttrium complexes" Gribkov, D. V.; Hultzsch, K. C. Chem. Commun. 2004, 730-731. PDF

  38. "Synthesis and Characterization of New Biphenolate and Binaphtholate Rare Earth Metal Amido Complexes. Catalysts for Asymmetric Olefin Hydroamination/Cyclization." Gribkov, D. V.; Hultzsch, K. C.; Hampel, F. Chem. Eur. J. 2003, 9, 4796-4810. PDF

  39. "Synthesis and Characterization of a Tetranuclear Hydride Cluster of Yttrium [{(η5-C5Me4SiMe3)Y}4(μ-H)43-H)4(THF)2]" Hultzsch, K. C.; Voth, P.; Spaniol, T. P.; Okuda, J. Z. Anorg. Allg. Chem. 2003, 629, 1272-1276. PDF
  40. "Alkylidene and Metalacyclic Complexes of Tungsten that Contain a Chiral Biphenoxide Ligand. Synthesis, Asymmetric Ring-Closing Metathesis, and Mechanistic Investigations." Tsang, W. C. P.; Hultzsch, K. C.; Alexander, J. B.; Bonitatebus, Jr., P. J., Schrock, R. R.; Hoveyda, A. H. J. Am. Chem. Soc. 2003, 125, 2652-2666. PDF
  41. "Group 3 and 4 metal alkyl and hydrido complexes containing a linked amido-cyclopentadienyl ligand: 'constrained geometry' polymerization catalysts for nonpolar and polar monomers" Arndt, S.; Beckerle, K.; Hultzsch, K. C.; Sinnema, P.-J.; Voth, P.; Spaniol, T. P.; Okuda, J. J. Mol. Catal. A: Chemical 2002, 190, 215-223. PDF
  42. "The First Polymer-Supported and Recyclable Chiral Catalyst for Enantioselective Olefin Metathesis" Hultzsch, K. C.; Jernelius, J. A.; Hoveyda, A. H.; Schrock, R. R. Angew. Chem. Int. Ed. 2002, 41, 589-593; Angew. Chem. 2002, 114, 609-613 English PDF
    Diese Arbeit wurde in Chemical&Engineering News (Ausgabe vom 18. Februar 2002, Seite 13), Science 2002, 295, 1605 und dem Titelbild von Chemical Reviews (Ausgabe vom October 2002) hervorgehoben.
  43. "Molybdenum Imido Alkylidene Complexes Containing Biphen Ligands that Have Silyl Groups Attached through the 6 and 6' Methyl Group Carbon Atoms" Hultzsch, K. C.; Bonitatebus, Jr., P. J.; Jernelius, J.; Schrock, R. R.; Hoveyda, A. H. Organometallics 2001, 20, 4705-4712. PDF
  44. "Polymerization Catalysts Based on Neutral and Cationic 12-Electron Alkyl and Hydrido Complexes" Okuda, J.; Arndt, S.; Beckerle, K.; Hultzsch, K. C.; Sinnema, P.-J.; Voth, P.; Spaniol, T. P. Advances on Organometallic Catalysts and Olefin Polymerization in China and Germany ; Sun, J., Janiak, C. Ed.; Chemical Industry Press, 2001, p. 217–225.
  45. "Rare Earth half-sandwich catalysts for the homo- and copolymerization of ethylene and styrene" Okuda, J.; Arndt, S.; Beckerle, K.; Hultzsch, K. C.; Voth, P.; Spaniol, T. P. Organomet. Catal. Olefin Polym.; Blom, R., Ed.; Springer-Verlag: Berlin, 2001, p. 156-165.
  46. "Rare Earth metal-based catalysts for the polymerization of nonpolar and polar monomers" Okuda, J.; Arndt, S.; Beckerle, K.; Hultzsch, K. C.; Voth, P.; Spaniol, T. P. Pure Appl. Chem. 2001, 73, 351-354. PDF
  47. "Synthesis of Molybdenum Imido Alkylidene Complexes that Contain 3,3'-Dialkyl-5,5',6,6'-tetramethyl-1,1'-biphenyl-2,2'-diolates (Alkyl = t-Bu or Adamantyl). Catalysts for Enantioselective Olefin Metathesis Reactions." Alexander, J. B.; Schrock, R. R.; Davis, W. M.; Hultzsch, K. C.; Hoveyda, A. H.; Houser, J. H. Organometallics 2000, 19, 3700-3715. PDF
  48. "Single-Component Polymerization Catalysts for Ethylene and Styrene: Synthesis, Characterization, and Reactivity of Alkyl and Hydrido Yttrium Complexes Containing a Linked Amido-Cyclopentadienyl Ligand" Hultzsch, K. C.; Voth, P.; Beckerle, K.; Spaniol, T. P.; Okuda, J. Organometallics 2000, 19, 228-243. PDF
  49. "Ring-opening polymerization of lactides using heterobimetallic yttrocene complexes" Beckerle, K.; Hultzsch, K. C.; Okuda, J. Macromol. Chem. Phys. 1999, 200, 1702 -1707. PDF
  50. "Polymerization of Ethylene, Styrene, and Acrylic Monomers Using Linked Amido-Cyclopentadienyl Metal Complexes" Okuda, J.; Amor, F.; Eberle, T.; Hultzsch, K. C.; Spaniol, T. P. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1999, 40(1), 371-372.
  51. "Half-Sandwich Alkyl and Hydrido Complexes of Yttrium: Convenient Synthesis and Polymerization Catalysis of Polar Monomers" Hultzsch, K. C.; Spaniol, T. P.; Okuda, J. Angew. Chem. Int. Ed. 1999, 38, 227 – 230; Angew. Chem. 1999, 111, 163-166. English PDF German PDF
  52. "Zirconium, hafnium, and yttrium complexes containing two linked amido-tetramethylcyclopentadienyl ligands: Synthesis, reactivity and molecular structure of Hf(η51-C5Me4SiMe2NiPr)2" Okuda, J.; Amor, F.; du Plooy, K. E.; Eberle, T.; Hultzsch, K. C.; Spaniol, T. P. Polyhedron 1998, 17, 1073-1080. PDF
  53. "Synthesis and Characterization of Yttrium Complexes Containing A Tridentate Linked Amido-Cyclopentadienyl Ligand"  Hultzsch, K. C.; Spaniol, T. P.; Okuda, J. Organometallics 1998, 17, 485-488. PDF
  54. "Chiral Lanthanocene Derivatives Containing Two Linked Amido-Cyclopentadienyl Ligands: Heterobimetallic Structure and Lactone Polymerization Activity" Hultzsch, K. C.; Spaniol, T. P.; Okuda, J. Organometallics 1997, 16, 4845-4856. PDF
  55. "Polymerization of ε-Caprolactone Using Heterobimetallic Lanthanocene Complexes" Hultzsch, K. C.; Okuda, J. Macromol. Rapid Commun. 1997, 18, 809-815. PDF
  56. "Thermal and Transition-Metal-Catalyzed Ring-Opening Polymerization (ROP) of [1]Silaferrocenophanes with Chlorine Substituents at Silicon: A Route to Tunable Poly(ferrocenylsilanes)" Zechel, D. L.; Hultzsch, K. C.; Rulkens, R.; Balaishis, D.; Ni, Y.; Pudelski, J. K.; Lough, A. J.; Manners, I.; Foucher, D. A. Organometallics 1996, 15, 1972-1978. PDF
  57. "Synthesis, Characterization, and Homopolymerization and Copolymerization Behavior of the Silicon-Bridged [1]Chromarenophane Cr(η-C6H5)2SiMe2" Hultzsch, K. C.; Nelson, J. M.; Lough, A. J.; Manners, I. Organometallics 1995, 14, 5496-5502. PDF

 

Patente

  1. "Binuclear metal hydride complexes as catalysts for the (co)polymerization of polar monomers" Okuda, J.; Hultzsch, K. C.; Geprägs, M. EP 0980873, 2000; JP 2000178280, 2000; US 6291655, 2001.
  2. "Nonbridged, mononuclear dialkylmetal half-sandwich complexes of rare earth metals and their use as catalysts for the (co)polymerization of olefinically unsaturated monomers" Okuda, J.; Hultzsch, K. C.; Geprägs, M. EP 0980875, 2000; JP 2000178293, 2000
  3. "Method for (co)polymerizing polar and non-polar monomers" Geprägs, M.; Queisser, J.; Okuda, J.; Hultzsch, K. C.; Beckerle, K. DE 19959252, 2001; WO 01/42314, 2001; US 6599996, 2003; JP 2004500450, 2004.
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